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在硅酸盐电解液体系中用不同极间距制备汽车用镁合金表面微弧氧化(MAO)层.对比不同极间距(40、120、200、280、360 mm)的涂层微观结构,设计电化学试验,分析极间距对涂层耐蚀性的影响.结果表明:将极间距增至200 mm,涂层表面平整,微孔较小,且均匀分布,缺陷数量低,致密度更高.MAO层由内部致密层与外部疏松层构成,致密层和基体结合层厚度较小.以不同极间距制备的涂层元素与物相成分基本一致.增大极间距后,涂层厚度降低,正面涂层厚度比反面大,在距离达到200 mm前,正反面涂层厚度相近.当距离达到200 mm时,腐蚀电流密度最小,涂层耐蚀性最优,涂层耐蚀能力可通过设定极间距调节. 相似文献
44.
Yi Chen Weijian Sun Haonan Zheng Changhao Li Bo Zhang Baoxiang Wang Chuncheng Hao 《Ceramics International》2021,47(17):24080-24091
In this paper, a novel H2Ti2O5@MoS2@SiO2 ternary composite material was prepared by a combination of dual hydrothermal method and controlled hydrolysis method, in which H2Ti2O5 nanotubes are tightly combined with hierarchical molybdenum disulfide, and the unique structure of titanate nano whiskers, including the loosely bound alkali metal ions between the titanate layers with high dielectric constant and the large aspect ratio, which induce active response to the electric field. Flower-like molybdenum disulfide provides electrical conductivity, and silicon dioxide as a insulative coating layer can suppress excessive the electrical conductivity of the two-dimensional material. The morphological evolution was studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results of showed that the sheet-shaped molybdenum disulfide coated with curved H2Ti2O5 nanotubes showed a honeycomb structure with uniform size. Silicon oxide acts as a cladding layer to increase the thickness of the flakes. The existence of H2Ti2O5, molybdenum disulfide and silicon dioxide is confirmed by X-ray powder diffractometer (XRD) and Fourier transform infrared spectroscopy (FT-IR). The prepared product was confirmed by XPS, BET test and electrorheological rheometer. Core/shell nanoparticles not only exert the active response characteristics of titanate nanoparticles and molybdenum disulfide to electric field, but also inherit the excellent characteristics of a core-shell structure produced by the interface polarization and the synergistic effect of the polar groups on the surface of the two-dimensional material further enhance the electrorheological effect. 相似文献
45.
Haiyang Chen Bin Li Xue Yang Guangqi Li Hongqiang Chen Junhong Chen Bo Ren 《Ceramics International》2021,47(16):22911-22917
Understanding the spheroidization process of micron-scaled α-Al2O3 powder in hydrothermal method is of great importance but still not completely revealed. The results demonstrated that SO42? played a significant role in the formation of spherical powder, while the bubble generated from the reaction of urea didn't work in the spheroidization process. The spheroidization process was summed up as two steps. The first was that SO42? limited the hydrolysis of Al3+ and reacted with Al3+ and OH- to form Al4(OH)10SO4, which nucleated and agglomerated into granular precipitates. The second was Ostwald ripening, which gave the spherical precursors a double-layered structure. When the spherical precursors obtained 120 °C were sintered at 1200 °C, α-Al2O3 were got and the spherical morphology still maintained with a large number of nano-sized pores. We anticipate the spherical α-Al2O3 with nano-sized pores can be applied in adsorption and filtration industries. 相似文献
46.
以5-溴-2-甲氧基吡啶为原料,经取代、过氧化、脱甲基化3步制备了5-甲磺酰基-1H-吡啶-2-酮.取代过程选用正丁基锂先与5-溴-2-甲氧基吡啶进行卤素-锂交换反应,再用二甲基二硫醚进行亲核取代,反应彻底且收率较高.过氧化过程选用间氯过氧苯甲酸作为过氧化剂,将甲硫基氧化为甲磺酰基,此步选用n(2-甲氧基-5-甲硫基吡啶)∶n(间氯过氧苯甲酸)=1.00∶2.50的投料比,有较好的收率.在脱甲基化过程中选用氢溴酸醋酸溶液进行脱甲基化,目标产物直接在醋酸中析出,提纯较为简便.目标产物的总收率为58.03%,其结构经1H NMR、13C NMR和IR确证.该方法操作简单,收率较高,易提纯,可大批量生产. 相似文献
47.
Yafei Liu Zhilong Fu Xingyu Chen Yaxin Wei Bo Zhang Aimin Chang 《Journal of the American Ceramic Society》2021,104(5):2134-2142
Rare-earth ions doped Ca0.9R0.1CeNbMoO8 (R = Y, Sm, Nd, La) ceramics have been successfully prepared by solid-state method, and their modifications to the microstructure and electrical properties are also investigated. The rare-earth ions doped ceramics exhibit the scheelite structure. With the increase in the radius of rare-earth ions, the lattice distortion and bond interaction will be enhanced, and the consistency of grain size will be reduced. The ceramics exhibit negative temperature coefficient (NTC) thermistor characteristics in the temperature range of 473 K-1273 K, and the activation energy decreases with the increase of the radius of rare-earth ions. Rare-earth ions doping can increase the content of Ce3+ ions and promote the conductivity of ceramics. Except for Sm3+-doped ceramics, the high-temperature aging rate of other ceramics is less than 2%. The existence of some metastable Sm2+ ions in Sm3+-doped ceramics not only increases the activation energy, but also reduces the high-temperature stability of the ceramics. 相似文献
49.